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Enantioselective Photocycloaddition of 3-Hydroxyflavones: Total Syntheses and Absolute Configuration Assignment of (+)-Ponapensin and (+)-Elliptifoline

We have previously reported development of biomimetic, asymmetric [3+2] photocycloadditions between 3-hydroxyflavones and cinnamate dipolarophiles to access (−)-rocaglamide and related natural products. Herein, we describe enantioselective syntheses of aglain cycloadducts leading to the first total...

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Detalhes bibliográficos
Main Authors: Lajkiewicz, Neil J., Roche, Stéphane P., Gerard, Baudouin, Porco, John A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3529213/
https://ncbi.nlm.nih.gov/pubmed/22804454
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305342f
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