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Parallel β-sheet vibrational couplings revealed by 2D IR spectroscopy of an isotopically labeled macrocycle: Quantitative benchmark for the interpretation of amyloid and protein infrared spectra

Infrared spectroscopy is playing an important role in the elucidation of amyloid fiber formation, but the coupling models that link spectra to structure are not well tested for parallel β-sheets. Using a synthetic macrocycle that enforces a two stranded parallel β-sheet conformation, we measured the...

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Detalhes bibliográficos
Main Authors: Woys, Ann Marie, Almeida, Aaron M., Wang, Lu, Chiu, Chi Cheng, McGovern, Michael, de Pablo, Juan J., Skinner, James L., Gellman, Samuel H., Zanni, Martin T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3523199/
https://ncbi.nlm.nih.gov/pubmed/23113791
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3074962
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