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Synthesis of Enantiomerically Enriched Imidazolidin-2-Ones via Asymmetric Pd-Catalyzed Alkene Carboamination Reactions
A catalyst composed of Pd(2)(dba)(3) and (S)-Siphos-PE is effective for the enantioselective coupling of N-allyureas with aryl bromides to afford 4-substituted imidazolidin-2-ones with up to 95% ee. Added water leads to significantly improved enantioselectivities with electron-poor aryl halide subst...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3517004/ https://ncbi.nlm.nih.gov/pubmed/22936415 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201205233 |
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