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Intramolecular Gas Phase Reactions of Synthetic Non-heme Oxoiron(IV) Ions: Proximity and Spin-State Reactivity Rules

The intramolecular gas phase reactivity of four oxoiron(IV) complexes supported by tetradentate N4 ligands (L) has been studied by means of tandem mass spectrometry measurements where the gas-phase ions [Fe(IV)(O)(L)(OTf)](+) and [Fe(IV)(O)(L)](2+) were isolated and then allowed to fragment by colli...

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Autors principals: Mas-Ballesté, Rubén, McDonald, Aidan R., Reed, Dana, Usharani, Dandamudi, Schyman, Patric, Milko, Petr, Shaik, Sason, Que, Lawrence
Format: Artigo
Idioma:Inglês
Publicat: 2012
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3516915/
https://ncbi.nlm.nih.gov/pubmed/22837063
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201200105
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