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Fundamental Role of Exchange-Enhanced Reactivity in C-H Activation by S=2 Oxoiron(IV) Complexes
[Image: see text] It is shown that H-abstraction reactivity by oxoiron(IV) complexes with a quintet ground state is highly enhanced due to exchange-stabilization endowed by the increased number of the exchange d-d interactions near the transition state. It is postulated that nonheme enzymes evolved...
Gorde:
| Egile Nagusiak: | , , , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2010
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2882195/ https://ncbi.nlm.nih.gov/pubmed/20358569 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201000004 |
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