Carregant...
Fundamental Role of Exchange-Enhanced Reactivity in C-H Activation by S=2 Oxoiron(IV) Complexes
[Image: see text] It is shown that H-abstraction reactivity by oxoiron(IV) complexes with a quintet ground state is highly enhanced due to exchange-stabilization endowed by the increased number of the exchange d-d interactions near the transition state. It is postulated that nonheme enzymes evolved...
Guardat en:
| Autors principals: | , , , , |
|---|---|
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2010
|
| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2882195/ https://ncbi.nlm.nih.gov/pubmed/20358569 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201000004 |
| Etiquetes: |
Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!
|