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Catalytic Enantioselective Allylic Amination of Unactivated Terminal Olefins via an Ene Reaction/[2,3]-Rearrangement

The enantioselective allylic amination of unactivated terminal olefins represents a direct and attractive strategy for the synthesis of enantioenriched amines. We have developed the first use of a nitrogen-containing reagent and a chiral palladium catalyst to convert unfunctionalized olefins into en...

Täydet tiedot

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Bibliografiset tiedot
Päätekijät: Bao, Hongli, Tambar, Uttam K.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2012
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC3511869/
https://ncbi.nlm.nih.gov/pubmed/23106555
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307851b
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