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Synthesis of conformationally restricted glutamate and glutamine derivatives from carbonylation of orthopalladated phenylglycine derivatives
A new method for the regioselective synthesis of 2-alkoxycarbonyl- and 2-(aminocarbonyl)phenylglycinate methyl esters has been developed. The reaction of the orthopalladated complex [Pd(μ-Cl)(C(6)H(4)(CH(CO(2)Me)NMe(2))-2)](2) (1) with nucleophiles HNu under a CO atmosphere results in the selective...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3510988/ https://ncbi.nlm.nih.gov/pubmed/23209488 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.179 |
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