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Guidelines for tunneling in enzymes
Here we extend the engineering descriptions of simple, single-electron-tunneling chains common in oxidoreductases to quantify sequential oxidation-reduction rates of two-or-more electron cofactors and substrates. We identify when nicotinamides may be vulnerable to radical mediated oxidation-reductio...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3509937/ https://ncbi.nlm.nih.gov/pubmed/20460101 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbabio.2010.04.441 |
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