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Cage Escape Competes with Geminate Recombination during Alkane Hydroxylation by the Diiron Oxygenase AlkB()
Three structurally analogous radical clock substrates with a 100-fold span in their rearrangement rates are hydroxylated by the diiron oxygenase AlkB to afford similar amounts of rearranged and unrearranged products. Such a result is predicted by a mechanistic scheme by which radical rebound compete...
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| Main Authors: | , , , , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2008
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3500147/ https://ncbi.nlm.nih.gov/pubmed/18512839 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200801184 |
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