Llwytho...

Parallel and Competitive Pathways for Substrate Desaturation, Hydroxylation and Radical Rearrangement by the Non-heme Diiron Hydroxylase AlkB

A purified and highly active form of the non-heme diiron hydroxylase AlkB was investigated using the diagnostic probe substrate norcarane. The reaction afforded C2 (26%) and C3 (43%) hydroxylation and desaturation products (31%). Initial C-H cleavage at C2 led to 7% C2 hydroxylation and 19% 3-hydrox...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Cooper, Harriet L. R., Mishra, Girish, Huang, Xiongyi, Pender-Cudlip, Marilla, Austin, Rachel N., Shanklin, John, Groves, John T.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2012
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC3531984/
https://ncbi.nlm.nih.gov/pubmed/23157204
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3059149
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