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Controlled Oxidation of Remote sp(3) C–H Bonds in Artemisinin via P450 Catalysts with Fine-Tuned Regio- and Stereoselectivity
[Image: see text] The selective oxyfunctionalization of isolated sp(3) C–H bonds in complex molecules represents a formidable challenge in organic chemistry. Here, we describe a rational, systematic strategy to expedite the development of P450 oxidation catalysts with refined regio- and stereoselect...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
American Chemical Society
2012
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| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3498520/ https://ncbi.nlm.nih.gov/pubmed/23121379 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3073462 |
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