Aspartyl Oxidation Catalysts That Dial In Functional Group Selectivity, along with Regio- and Stereoselectivity

[Image: see text] A remarkable aspect of enzyme evolution is the portability of catalytic mechanisms for fundamentally different chemical reactions. For example, aspartyl proteases, which contain two active site carboxylic acid groups, catalyze the hydrolysis of amide bonds, while glycosyltransferas...

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Bibliographic Details
Published in:ACS Cent Sci
Main Authors: Alford, Joshua S., Abascal, Nadia C., Shugrue, Christopher R., Colvin, Sean M., Romney, David K., Miller, Scott J.
Format: Artigo
Language:Inglês
Published: American Chemical Society 2016
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5084076/
https://ncbi.nlm.nih.gov/pubmed/27800556
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00237
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