Aspartyl Oxidation Catalysts That Dial In Functional Group Selectivity, along with Regio- and Stereoselectivity

[Image: see text] A remarkable aspect of enzyme evolution is the portability of catalytic mechanisms for fundamentally different chemical reactions. For example, aspartyl proteases, which contain two active site carboxylic acid groups, catalyze the hydrolysis of amide bonds, while glycosyltransferas...

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Publicat a:ACS Cent Sci
Autors principals: Alford, Joshua S., Abascal, Nadia C., Shugrue, Christopher R., Colvin, Sean M., Romney, David K., Miller, Scott J.
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2016
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5084076/
https://ncbi.nlm.nih.gov/pubmed/27800556
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00237
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