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Capturing fleeting intermediates in a catalytic C–H amination reaction cycle
We have applied an ambient ionization technique, desorption electrospray ionization MS, to identify transient reactive species of an archetypal C–H amination reaction catalyzed by a dirhodium tetracarboxylate complex. Using this analytical method, we have detected previously proposed short-lived rea...
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Main Authors: | , , , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
National Academy of Sciences
2012
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3494934/ https://ncbi.nlm.nih.gov/pubmed/23091019 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1207600109 |
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