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Rhodium-Catalyzed Acyloxy Migration of Propargylic Esters in Cycloadditions, Inspiration from Recent “Gold Rush”

Transition metal-catalyzed acyloxy migration of propargylic esters offers versatile entries to allene and vinyl carbene intermediates for various fascinating subsequent transformations. Most π-acidic metals (e.g. gold and platinum) are capable of facilitating these acyloxy migration events. However,...

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Hlavní autoři: Shu, Xing-Zhong, Shu, Dongxu, Schienebeck, Casi M., Tang, Weiping
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3491182/
https://ncbi.nlm.nih.gov/pubmed/22895533
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cs35235d
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