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Gas-phase pyrolytic formation and dimerization of benzocyclobutenes: Synthesis of [2(4)](1,2,4,5) cyclophane

Gas-phase pyrolysis of benzocyclobutenes in a nitrogen stream at 450°C is a convenient efficient method for preparing dibenzocyclooctadienes. Application of this method to benzo[1,2;4,5]dicyclobutene gives [2(4)](1,2,4,5)cyclophane directly. However, under the same reaction conditions, 3,6-dimethylb...

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發表在:Proc Natl Acad Sci U S A
Main Authors: Eaton, Bruce E., Laganis, E. D., Boekelheide, V.
格式: Artigo
語言:Inglês
出版: National Academy of Sciences 1981
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在線閱讀:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC349087/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/16593108/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.78.11.6564
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