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Gas-phase pyrolytic formation and dimerization of benzocyclobutenes: Synthesis of [2(4)](1,2,4,5) cyclophane

Gas-phase pyrolysis of benzocyclobutenes in a nitrogen stream at 450°C is a convenient efficient method for preparing dibenzocyclooctadienes. Application of this method to benzo[1,2;4,5]dicyclobutene gives [2(4)](1,2,4,5)cyclophane directly. However, under the same reaction conditions, 3,6-dimethylb...

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Detalhes bibliográficos
Main Authors: Eaton, Bruce E., Laganis, E. D., Boekelheide, V.
Formato: Artigo
Idioma:Inglês
Publicado em: 1981
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC349087/
https://ncbi.nlm.nih.gov/pubmed/16593108
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