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A Torquoselective 6π Electrocyclization Approach to Reserpine Alkaloids
[Image: see text] A highly torquoselective thermal triene 6π electrocyclization controls the relative stereochemistry between the C3 and C18 stereocenters of the dodecahydroindolo[2,3-a]benzo[g]quinolizine skeleton of reserpine-type alkaloids. Employing a tandem cross-coupling/electrocyclization pro...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3488149/ https://ncbi.nlm.nih.gov/pubmed/23039026 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol302265z |
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