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Synthesis and Reduction Kinetics of Sterically Shielded Pyrrolidine Nitroxides
[Image: see text] A series of sterically shielded pyrrolidine nitroxides were synthesized and their reduction by ascorbate (vitamin C) indicate that nitroxide 3 – a tetraethyl derivative of 3-carboxy-PROXYL – is reduced at the slowest rate among known nitroxides, i.e., at a 60-fold slower rate than...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3486517/ https://ncbi.nlm.nih.gov/pubmed/23050653 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol302506f |
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