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Synthesis and Reduction Kinetics of Sterically Shielded Pyrrolidine Nitroxides

[Image: see text] A series of sterically shielded pyrrolidine nitroxides were synthesized and their reduction by ascorbate (vitamin C) indicate that nitroxide 3 – a tetraethyl derivative of 3-carboxy-PROXYL – is reduced at the slowest rate among known nitroxides, i.e., at a 60-fold slower rate than...

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Autors principals: Paletta, Joseph T., Pink, Maren, Foley, Bridget, Rajca, Suchada, Rajca, Andrzej
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3486517/
https://ncbi.nlm.nih.gov/pubmed/23050653
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol302506f
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