Palladium(II)-Catalyzed Regioselective Ortho Arylation of sp(2) C—H Bonds of N-Aryl-2-amino Pyridine Derivatives

ABSTRACT: The direct arylation of N-(2-pyridyl) substituted anilines is described. Arylation takes place in ortho position to the amine functionality and is directed by the pyridine N-substituent. Remarkably, N-arylation was never observed as a competing process even though conditions also suitable...

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Главные авторы: Koley, Moumita, Dastbaravardeh, Navid, Schnürch, Michael, Mihovilovic, Marko D
Формат: Artigo
Язык:Inglês
Опубликовано: WILEY-VCH Verlag 2012
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC3483625/
https://ncbi.nlm.nih.gov/pubmed/23136619
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cctc.201200155
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