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Direct Stereospecific Amination of Alkyl and Aryl Pinacol Boronates

The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.

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Bibliografske podrobnosti
Main Authors: Mlynarski, Scott N., Karns, Alexander S., Morken, James P.
Format: Artigo
Jezik:Inglês
Izdano: 2012
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3481838/
https://ncbi.nlm.nih.gov/pubmed/23002712
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305448w
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