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Stereospecific Cross-Coupling of Secondary Organotrifluoroborates: Potassium 1-(Benzyloxy)alkyltrifluoroborates

Potassium 1-(alkoxy/acyloxy)alkyltrifluoroborates have been synthesized through a copper-catalyzed diboration of aldehydes and subsequent conversion of the resulting potassium 1-(hydroxy)alkyltrifluoroborates. The palladium-catalyzed Suzuki-Miyaura reaction employing the potassium 1-(benzyloxy)alkyl...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Molander, Gary A., Wisniewski, Steven R.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3481220/
https://ncbi.nlm.nih.gov/pubmed/23025482
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja307861n
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