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Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase.

Several properties of the FeMo-cofactor (co) of nitrogenase in N-methylformamide solution at ambient temperature have been investigated by means of 19F NMR spectroscopy. With C6H5CF3 reference signals the magnetic moment per Mo atom was found to be approximately equal to 3.9 BM, consistent with S =...

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Xehetasun bibliografikoak
Egile Nagusiak: Mascharak, P K, Smith, M C, Armstrong, W H, Burgess, B K, Holm, R H
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 1982
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC347274/
https://ncbi.nlm.nih.gov/pubmed/6960364
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