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Femtosecond Conical Intersection Dynamics of Tryptophan in Proteins and Validation of Slowdown of Hydration Layer Dynamics
Water motion probed by intrinsic tryptophan shows the significant slowdown around protein surfaces but it is unknown how the ultrafast internal conversion of two nearly degenerate states of Trp ((1)L(a) and (1)L(b)) affects the initial hydration in proteins. Here, we used a mini-protein with ten dif...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3468670/ https://ncbi.nlm.nih.gov/pubmed/22992183 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305283j |
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