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Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H(2) evolution by [Ni(P(2)N(2))(2)](2+) complexes
The electrocatalytic reduction of protons to H(2) by [Image: see text] (where [Image: see text] in the highly acidic ionic liquid dibutylformamidium bis(trifluoromethanesulfonyl)amide shows a strong dependence on added water. A turnover frequency of 43,000–53,000 s(-1) has been measured for hydrogen...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3465405/ https://ncbi.nlm.nih.gov/pubmed/22685211 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1120208109 |
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