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Use of un-derivatized thyroid hormones for photoaffinity labeling of binding proteins.

Irradiation of the thyroid hormones thyroxine and 3,5,3'-triiodothyronine in the near UV (greater than 300 nm) causes homolytic fission of C--I bonds in both rings. In the presence of hormone-binding proteins, the phenyl radical thus formed, and possibly also the iodine radical, can establish a cova...

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Udgivet i:Proc Natl Acad Sci U S A
Principais autores: van der Walt, B, Nikodem, V M, Cahnmann, H J
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 1982
Fag:
Research Article
Online adgang:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC346450/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/6954496/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.79.11.3508
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