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Recyclable fluorous cinchona alkaloid ester as a chiral promoter for asymmetric fluorination of β-ketoesters

A fluorous cinchona alkaloid ester has been developed as a chiral promoter for the asymmetric fluorination of β-ketoesters. It has comparable reactivity and selectivity to the nonfluorous versions of cinchona alkaloids and can be easily recovered from the reaction mixture by simple fluorous solid-ph...

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Detalhes bibliográficos
Main Authors: Yi, Wen-Bin, Huang, Xin, Zhang, Zijuan, Zhu, Dian-Rong, Cai, Chun, Zhang, Wei
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3458743/
https://ncbi.nlm.nih.gov/pubmed/23019453
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.138
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