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Synthetic Applications and Inversion Dynamics of Configurationally Stable 2-Lithio-2-aryl-Pyrrolidines and -Piperidines
In diethyl ether, N-Boc-2-lithio-2-arylpiperidines have been found to be configurationally stable at −80 °C whereas N-Boc-2-lithio-2-arylpyrrolidines are configurationally stable at −60 °C. Several tertiary benzylic carbanions derived from enantioenriched 2-aryl heterocycles have been successfully a...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3443602/ https://ncbi.nlm.nih.gov/pubmed/22881214 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja306276w |
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