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o-(Trialkylstannyl)anilines and Their Utility in Stille Cross-Coupling: Direct Introduction of the 2-Aminophenyl Substituent

We have developed shelf- and air-stable ortho-stannylated aniline reagents that can directly be coupled with alkenyl and aryl halides via Stille cross-coupling. We report i) the efficient preparation of o-(tributylstannyl)aniline (2a) and o-(trimethylstannyl)aniline (2b), ii) the comparison of the r...

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Détails bibliographiques
Auteurs principaux: Izgu, Enver Cagri, Hoye, Thomas R.
Format: Artigo
Langue:Inglês
Publié: 2012
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3439219/
https://ncbi.nlm.nih.gov/pubmed/22984300
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2012.06.138
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