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Synthesis of Enantioenriched α-(Hydroxyalkyl)-tri-n-butylstannanes
[Image: see text] A catalytically asymmetric synthesis of α-(hydroxyalkyl)-tri-n-butylstannanes 1 in good-excellent yields and enantioselectivities (up to 98% e.e.) via addition of ethyl(tri-n-butylstannyl)zinc to aldehydes was achieved. In practice, 1 was isolated after protection as its more stabl...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3436603/ https://ncbi.nlm.nih.gov/pubmed/18646026 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200802313 |
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