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Rate of Interfacial Electron Transfer through the 1,2,3-Triazole Linkage

The rate of electron transfer is measured to two ferrocene and one iron tetraphenylporphyrin redox species coupled through terminal acetylenes to azide-terminated thiol monolayers by the Cu(I)-catalyzed azide–alkyne cycloaddition (a Sharpless “click” reaction) to form the 1,2,3-triazole linkage. The...

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Bibliografiske detaljer
Main Authors: Devaraj, Neal K., Decreau, Richard A., Ebina, Wataru, Collman, James P., Chidsey, Christopher E. D.
Format: Artigo
Sprog:Inglês
Udgivet: 2006
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3434967/
https://ncbi.nlm.nih.gov/pubmed/16898751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp057416p
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