A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux

We studied the selectivity of a functional model of cytochrome c oxidase's active site that mimics the coordination environment and relative locations of Fe(a3), Cu(B), and Tyr(244). To control electron flux, we covalently attached this model and analogs lacking copper and phenol onto self-asse...

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Bibliografiske detaljer
Main Authors: Collman, James P., Devaraj, Neal K., Decréau, Richard A., Yang, Ying, Yan, Yi-Long, Ebina, Wataru, Eberspacher, Todd A., Chidsey, Christopher E. D.
Format: Artigo
Sprog:Inglês
Udgivet: 2007
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3064436/
https://ncbi.nlm.nih.gov/pubmed/17363671
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1135844
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