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Rh(I)-Catalyzed Cyclocarbonylation of Allenol Esters to Prepare Acetoxy 4-Alkylidene Cyclopent-3-en-2-ones

[Image: see text] A Rh(I)-catalyzed cyclocarbonylation reaction of allenol esters has been examined and its synthetic viability established for the conversion of trisubstituted allenes to bicyclo-[4.3.0], and -[5.3.0] skeletons possessing an α-acetoxy cyclopentadienone. Tetrasubstituted allenol acet...

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Détails bibliographiques
Auteurs principaux: Brummond, Kay M., Davis, Matthew M., Huang, Chaofeng
Format: Artigo
Langue:Inglês
Publié: 2009
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3433757/
https://ncbi.nlm.nih.gov/pubmed/19821580
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901459t
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