Synthesis of 3'-phosphates of diribonucleoside monophosphates via phosphotriester intermediates.
Phosphorylation of the easily accessible 3',5'-diesters 1a-d with diphenyl phosphorochloridate, followed by selective 5'-deacylation, affords the phosphotriester derivatives 2a-d in good yields. Alkaline treatment of 2a-d results in the formation of the 2',3'-cyclic phosphates (3a-d). The usefulness...
Shranjeno v:
| izdano v: | Nucleic Acids Res |
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| Principais autores: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
Oxford University Press
1976
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| Online dostop: | https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC343124/ https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/995650/ https://ncbi.nlm.nih.govhttps://doi.org/10.1093/nar/3.10.2731 |
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