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A C(2)-Symmetric, Basic Fe(III) Carboxylate Complex Derived from a Novel Triptycene-Based Chelating Carboxylate Ligand
A triptycene-based bis(benzoxazole) diacid ligand H(2)L2(Ph4) bearing sterically encumbering groups was synthesized. Treatment of H(2)L2(Ph4) with Fe(OTf)(3) afforded a C(2)-symmetric trinuclear iron(III) complex, [NaFe(3)(L2(Ph4))(2)(μ(3)-O)(μ-O(2)CCPh(3))(2)(H(2)O)(3)](OTf)(2) (8). The triiron cor...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3418543/ https://ncbi.nlm.nih.gov/pubmed/22751622 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2dt31260c |
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