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Design and Synthesis of a Novel Triptycene-based Ligand for Modeling Carboxylate-Bridged Diiron Enzyme Active Sites
[Image: see text] A novel triptycene-based ligand with a pre-organized framework was designed to model carboxylate-bridged diiron activesites in bacterial multicomponent monooxygenase (BMM) hydroxylase enzymes. The synthesis of the bis(benzoxazole)-appended ligand L1 depicted was accomplished in 11...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2011
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3184322/ https://ncbi.nlm.nih.gov/pubmed/21875093 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201882v |
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