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Asymmetric hydrogenation of ketones: Tactics to achieve high reactivity, enantioselectivity, and wide scope
Ru complexes with chiral diphosphines and amine-based ligands achieve high catalytic activity and enantioselectivity for the hydrogenation of ketones under neutral to slightly basic conditions. The chiral environment is controllable by changing the combination of these two ligands. A concerted six-m...
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Japan Academy
2010
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3417846/ https://ncbi.nlm.nih.gov/pubmed/20228621 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.2183/pjab.86.202 |
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