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Dynamic Origin of the Stereoselectivity of a Nucleophilic Substitution Reaction

[Image: see text] A nucleophilic substitution on a dichlorovinyl ketone was studied experimentally and computationally. A mixture of products is observed experimentally, but a conventional computational analysis does not account for the formation of the minor stereoisomer. Instead, the product mixtu...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: Bogle, Xavier S., Singleton, Daniel A.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2012
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3417076/
https://ncbi.nlm.nih.gov/pubmed/22540965
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300817a
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