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Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates

[Image: see text] An iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates has been developed. The reactions proceed under mild conditions and provide E/Z selectivities of > 95:5 for 2-aryl and -heteroarylvinyl substrates. Experimental observations suggest that the reaction d...

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Hlavní autoři: Parsons, Andrew T., Senecal, Todd D., Buchwald, Stephen L.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3390237/
https://ncbi.nlm.nih.gov/pubmed/22328162
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201108267
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