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Iron(II)-Catalyzed Trifluoromethylation of Potassium Vinyltrifluoroborates
[Image: see text] An iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates has been developed. The reactions proceed under mild conditions and provide E/Z selectivities of > 95:5 for 2-aryl and -heteroarylvinyl substrates. Experimental observations suggest that the reaction d...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2012
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3390237/ https://ncbi.nlm.nih.gov/pubmed/22328162 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201108267 |
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