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Conformational consequences of ionization of Lys, Asp and Glu buried at position 66 in staphylococcal nuclease

The pK(a) values measured previously for the internal Lys-66, Asp-66 and Glu-66 in variants of a highly stable form of staphylococcal nuclease are shifted by as many as 5 pK(a) units relative to normal pK(a) values in water. These shifts cannot be reproduced with continuum electrostatics calculation...

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Detalhes bibliográficos
Main Authors: Karp, Daniel A., Stahley, Mary R., Bertrand, García-Moreno E.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3373020/
https://ncbi.nlm.nih.gov/pubmed/20329780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi902114m
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