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Double-Fold C-H Oxygenation of Arenes Using PyrDipSi: a General and Efficient Traceless/Modifiable Silicon-Tethered Directing Group
The efficient Pd-catalyzed double-fold C-H oxygenation of arenes into resorcinols using newly developed 2-pyrimidyldiisopropylsilyl (PyrDipSi) directing group is described. Its employment allows for a sequential introduction of OAc and OPiv groups in a one-pot manner to produce orthogonally protecte...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3371766/ https://ncbi.nlm.nih.gov/pubmed/22414133 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3010545 |
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