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Concise Total Synthesis and Stereochemical Revision of (+)-Naseseazines A and B. Regioselective Arylative Dimerization of Diketopiperazine Alkaloids

The concise and enantioselective total syntheses of (+)-naseseazines A and B are described. Our regioselective and directed dimerization of diketopiperazines provides their critical C3–C(sp2) linkages, an assembly with plausible biogenetic relevance. We revise the absolute stereochemistry of (+)-nas...

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Bibliografske podrobnosti
Main Authors: Kim, Justin, Movassaghi, Mohammad
Format: Artigo
Jezik:Inglês
Izdano: 2011
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3369503/
https://ncbi.nlm.nih.gov/pubmed/21875056
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja206743v
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