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Magnetic circular dichroism of ferrous carbonyl adducts of cytochromes P-450 and P-420 and their synthetic models: further evidence for mercaptide as the fifth ligand to iron.

Absorption and magnetic circular dichroism (MCD) spectra have been obtained for the ferrous carbonyl adducts of cytochromes P-450 and P-420 as well as synthetic model systems. Ferrous porphyrins with sodium methyl mercaptide and CO in benzene give MCD and absorption spectra which are almost identica...

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Veröffentlicht in:Proc Natl Acad Sci U S A
Hauptverfasser: Collman, J P, Sorrell, T N, Dawson, J H, Trudell, J R, Bunnenberg, E, Djerassi, C
Format: Artigo
Sprache:Inglês
Veröffentlicht: National Academy of Sciences 1976
Schlagworte:
Online-Zugang:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC335827/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/1061127/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.73.1.6
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