Magnetic circular dichroism of ferrous carbonyl adducts of cytochromes P-450 and P-420 and their synthetic models: further evidence for mercaptide as the fifth ligand to iron.

Absorption and magnetic circular dichroism (MCD) spectra have been obtained for the ferrous carbonyl adducts of cytochromes P-450 and P-420 as well as synthetic model systems. Ferrous porphyrins with sodium methyl mercaptide and CO in benzene give MCD and absorption spectra which are almost identica...

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Autors principals: Collman, J P, Sorrell, T N, Dawson, J H, Trudell, J R, Bunnenberg, E, Djerassi, C
Format: Artigo
Idioma:Inglês
Publicat: 1976
Matèries:
Research Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC335827/
https://ncbi.nlm.nih.gov/pubmed/1061127
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