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Hydrolysis of N-Alkyl Sulfamates and the Catalytic Efficiency of an S-N Cleaving Sulfamidase

The final step in the degradation of heparin sulfate involves the enzymatic hydrolysis of its 2-sulfamido groups. To evaluate the power of the corresponding sulfamidases as catalysts, we examined the reaction of N-neopentyl sulfamate at elevated temperatures and found it to undergo specific acid cat...

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Detalhes bibliográficos
Main Authors: Lohman, Danielle C., Wolfenden, Richard, Edwards, David R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3341085/
https://ncbi.nlm.nih.gov/pubmed/22352783
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo300198w
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