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Dispersion Energy Enforced Dimerization of a Cyclic Disilylated Plumbylene
[Image: see text] By reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with PbBr(2) in the presence of triethylphosphine a base adduct of a cyclic disilylated plumbylene could be obtained. Phosphine abstraction with B(C(6)F(5))(3) led to formation of a base-free plumb...
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| Autori principali: | , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2012
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3336735/ https://ncbi.nlm.nih.gov/pubmed/22455750 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300654t |
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