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Dispersion Energy Enforced Dimerization of a Cyclic Disilylated Plumbylene

[Image: see text] By reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with PbBr(2) in the presence of triethylphosphine a base adduct of a cyclic disilylated plumbylene could be obtained. Phosphine abstraction with B(C(6)F(5))(3) led to formation of a base-free plumb...

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Bibliografische gegevens
Hoofdauteurs: Arp, Henning, Baumgartner, Judith, Marschner, Christoph, Zark, Patrick, Müller, Thomas
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: American Chemical Society 2012
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3336735/
https://ncbi.nlm.nih.gov/pubmed/22455750
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300654t
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