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The XAS Model of the Copper(II)-Imidazole Complex Ion in Liquid Aqueous Solution: A Strongly Solvated Square Pyramid

Copper K-edge EXAFS and MXAN analyses were combined to evaluate the structure of the copper(II)-imidazole complex ion in liquid aqueous solution. Both methods converged to the same square pyramidal inner coordination sphere [Cu(Im)(4)L(ax)](2+), (L(ax) indeterminate) with four equatorial nitrogens a...

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Hlavní autoři: Frank, Patrick, Benfatto, Maurizio, Hedman, Britt, Hodgson, Keith O.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3328689/
https://ncbi.nlm.nih.gov/pubmed/22316238
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic2017819
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