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A high-resolution XAS study of aqueous Cu(II) in liquid and frozen solutions: Pyramidal, polymorphic, and non-centrosymmetric

High-resolution EXAFS (k = 18 Å(−1)) and MXAN XAS analyses show that axially elongated square pyramidal [Cu(H(2)O)(5)](2+) dominates the structure of Cu(II) in aqueous solution, rather than 6-coordinate JT-octahedral [Cu(H(2)O)(6)](2+). Freezing produced a shoulder at 8989.6 eV on the rising XAS edg...

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Dettagli Bibliografici
Pubblicato in:J Chem Phys
Autori principali: Frank, Patrick, Benfatto, Maurizio, Qayyam, Munzarin, Hedman, Britt, Hodgson, Keith O.
Natura: Artigo
Lingua:Inglês
Pubblicazione: AIP Publishing LLC 2015
Soggetti:
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC4349298/
https://ncbi.nlm.nih.gov/pubmed/25725734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4908266
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