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A high-resolution XAS study of aqueous Cu(II) in liquid and frozen solutions: Pyramidal, polymorphic, and non-centrosymmetric
High-resolution EXAFS (k = 18 Å(−1)) and MXAN XAS analyses show that axially elongated square pyramidal [Cu(H(2)O)(5)](2+) dominates the structure of Cu(II) in aqueous solution, rather than 6-coordinate JT-octahedral [Cu(H(2)O)(6)](2+). Freezing produced a shoulder at 8989.6 eV on the rising XAS edg...
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| Udgivet i: | J Chem Phys |
|---|---|
| Main Authors: | , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
AIP Publishing LLC
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4349298/ https://ncbi.nlm.nih.gov/pubmed/25725734 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4908266 |
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