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Synthesis and mesomorphic properties of calamitic malonates and cyanoacetates tethered to 4-cyanobiphenyls

4-Cyano-1,1'-biphenyl derivatives bearing ω-hydroxyalkyl substituents were reacted with methyl 3-chloro-3-oxopropionate or cyanoacetic acid, giving liquid-crystalline linear malonates and cyanoacetates. These compounds formed monotropic nematic phases at 62 °C down to ambient temperature upon c...

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Detalhes bibliográficos
Main Authors: Kress, Katharina C, Kaller, Martin, Axenov, Kirill V, Tussetschläger, Stefan, Laschat, Sabine
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3326613/
https://ncbi.nlm.nih.gov/pubmed/22509205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.8.40
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